>VS 2010 ( maybe 2008 )
>
>/ collapses the toolbox containers
>* opens them up
>
>ctrl ] moves to the matching closing bracket

Also, FWIW, works with XAML elements (and presumably XML)
Can also be a good idea to pick a more visible marker than the default:
Tools/Options/Environment/Fonts and Colors/Brace Matching (Highlight)

>
>ctrl - (as mentioned) to previous cursor position. ctrl-shift-hyphen to next browsed position.
>
>useful blog
>
>http://www.devcurry.com/2010/06/30-favorite-visual-studio-keyboard.html?showComment=1295484752539#c7645052696990081678

And when you really get bored assign your own at Environment/Keyboard :-}