First, I suggest you switch to MVC4. VWD is available.

I'm not that familiar with VWD, but in VS, you pick the language when you first create the project.

>I started exploring MVC3 with this site http://www.asp.net/mvc/tutorials/getting-started-with-aspnet-mvc3/vb/intro-to-aspnet-mvc-3. I started with VB.
>
>I would now like to use C#. Is there a way to indicate that to VWD (2010 Express)?