>Something like this example may be all you need (I've used a Dictionary rather than a basic collection - more efficient, better type safety):
>

Imports System.Collections.Generic
>Imports System.IO
>
>Namespace ConsoleApplication3
>	Class Program
>		Private Shared Sub Main(args As String())
>			Dim userA = New User() With { _
>				Key .Name = "Gary", _
>				Key .OperatorName = "Gary NiceGuy", _
>				Key .ID = "Gary", _
>				Key .AccessLevel = 4, _
>				Key .Password = "50564348" _
>			}
>			Dim userB = New User() With { _
>				Key .Name = "Tester", _
>				Key .OperatorName = "Tester Hester", _
>				Key .ID = "Tester", _
>				Key .AccessLevel = 1, _
>				Key .Password = "435242455243" _
>			}
>			Dim users = New Users()
>			users.Add(userA.Name, userA)
>			users.Add(userB.Name, userB)
>
>			Using sw As New StreamWriter("test.ini")
>				For Each v As var In users
>					sw.WriteLine("[" & v.Key & "]")
>					sw.WriteLine("OperatorID=" & v.Value.ID)
>					sw.WriteLine("OperatorName=" & v.Value.OperatorName)
>					sw.WriteLine("AccessLevel=" & v.Value.AccessLevel.ToString())
>					sw.WriteLine("OperatorPassword" & v.Value.Password)
>					sw.WriteLine()
>				Next
>			End Using
>		End Sub
>	End Class
>
>	Public Class User
>		Public Property ID() As String
>			Get
>				Return m_ID
>			End Get
>			Set
>				m_ID = Value
>			End Set
>		End Property
>		Private m_ID As String
>		Public Property Name() As String
>			Get
>				Return m_Name
>			End Get
>			Set
>				m_Name = Value
>			End Set
>		End Property
>		Private m_Name As String
>		Public Property OperatorName() As String
>			Get
>				Return m_OperatorName
>			End Get
>			Set
>				m_OperatorName = Value
>			End Set
>		End Property
>		Private m_OperatorName As String
>		Public Property Password() As String
>			Get
>				Return m_Password
>			End Get
>			Set
>				m_Password = Value
>			End Set
>		End Property
>		Private m_Password As String
>		Public Property LoggedIn() As [Boolean]
>			Get
>				Return m_LoggedIn
>			End Get
>			Set
>				m_LoggedIn = Value
>			End Set
>		End Property
>		Private m_LoggedIn As [Boolean]
>		Public Property AccessLevel() As Integer
>			Get
>				Return m_AccessLevel
>			End Get
>			Set
>				m_AccessLevel = Value
>			End Set
>		End Property
>		Private m_AccessLevel As Integer
>	End Class
>
>	Public Class Users
>		Inherits Dictionary(Of String, User)
>
>	End Class
>End Namespace

Thank you very much for your help on this.

The next question that I have is how I would go about using serialization and deserialization on an INI file.

Thank you