>Has anyone started to use VB.NET for Web Development? And how does it compare with tools like Web Connection?

ASP.NET is pretty nice. The pages you create a easier to maintain (alot less spaghetti code thanks to Web Forms) and they're easy to develop. Debugging a Web Form is pretty simple, you can step through the code while its running on the Web Server. Tasks that you find yourself doing over and over (like validating a web form, or creating a datalist or datagrid from a table) is a snap in ASP.NET.