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If you're more comfortable with curly brackets, semi-colons on the end of lines, and case sensitiviy, go with C#. If not, go with VB .NET.
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Talk about an over-simplification...< s >...

The proper rubric is which langauge - in the long run, will you be most productive in - but not at the expense of cutting off future flexibility. For example, if you know you will need to run un-managed code, the C# may be the clear choice.

Minor nuances of a language is an extremely "dumbed-down" way of analyzing the problem...< s >...