>I am using the VFP report form to print a report but I need to print a field that will add a SUPERSCRIPT character in the end of field. Can anyone tell me how to do it?
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What do you mean? Do you mean that you need to have a specific character added at the end of a string, or do you need to shift the vertical offset of the trailing character, or is this a native printer capability that you want to employ?

In order to have a different font used, you'll need to have two print fields; a field of a report can have only one font in it.

If it's a question of having a specific character appear at the end of a field, the easiest thing to do will be to use a font with the specific required character in it, and append the character to the end of the expression used for the print field.

In order to exploit specific printer behaviors not generically supported by Windows, you'll need to use a tool other than the VFP report writer to create your output.